1 author 2. . Classification Codes. 1, 2, 3 We report the accidental ingestion of ammonium dichromate by a child that led to the development of severe gastroenteritis, renal failure, hepatic injury, coagulopathy, coma, shock, and death. Ammonium dichromate is sometimes known as Vesuvian Fire, because of its use in demonstrations of tabletop "volcanoes". H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled. Skin manifestations after industrial exposure of chromate salts are well-known, but little is known about systemic toxicity and its treatment. Ammonium dichromate(VI), (NH 4) 2 Cr 2 O 7 (s), (VERY TOXIC, EXPLOSIVE, DANGEROUS FOR THE ENVIRONMENT) - see CLEAPSS Hazcard HC007. H301 - Toxic if swallowed. H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled. Poisoning in children by ammonium dichromate ,an odorless and bright orangered crystal, are rarely reported. . Acute ammonium dichromate poisoning in a 2 year-old child . doi: 10.4103/0972-5229.144024. Hemodialysis was promptly undertaken . . Company: Hummel Croton Inc. 10 Harmich Rd. Though the history was suggestive of ingestion of ammonium dichromate, I wonder why the authors did not estimate the blood level of chromium in their studied patient. Ammonium dichromate. Ammonium dichromate is a salt consisting of ammonium ions and dichromate ions, a toxic chemical salt used to sensitize organic emulsion. Danger. 1B - H360FD Acute Tox. Ammonium dichromate [Chromium and chromium compounds] Ammonium dichromate [UN1439] [Oxidizer] Chromic acid, diammonium salt. H317 May cause an allergic skin reaction. Do NOT be tempted to mix other chemicals with the ammonium dichromate (VI). FDA UNII. Ammonium dichromate is used in photo engraving, dye mordant, pigments, pickling, photography, process engraving, lithography, pyrotechnics, glazes for porcelain and china wares. Mol. Specific target organ toxicity - (repeated exposure) Category 1. Flame and sparks spread rapidly through the mass, and if confined, it may become explosive. King George's Medical University, Lucknow, India. ChemSpider ID 23002. Monoisotopic mass 251.914169 Da. Ammonium dichromateRevision Date 19-Jan-2018 Signal Word Danger Hazard Statements May intensify fire; oxidizer May form combustible dust concentrations in air Toxic if swallowed Harmful in contact with skin Fatal if inhaled Causes severe skin burns and eye damage May cause allergy or asthma symptoms or breathing difficulties if inhaled H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H330 - Fatal if inhaled. Chromium (Cr) is a strong oxidant and poisoning usually begins with gastrointestinal symptoms progressing to multiorgan failure. Poisoning in children by ammonium dichromate, an odorless and bright orange-red crystal, are rarely reported. The target organs that. H350 May cause cancer. Acute Toxicity (Inhalation) Category 2, Reproductive Toxicity Category 1B, Specific target organ toxicity - repeated Acute ammonium dichromate poisoning in a 2 year-old child Indian Journal of Critical Care Medicine, 2014, 18, 757-8 Menon Sunilkumar, Thekkuttuparambil Ajith, Vadakut Parvathy. H312 Harmful in contact with skin. H317 - May cause an allergic skin reaction. H340 May cause genetic defects. Acute toxicity, Oral (Category 3) Acute toxicity, Inhalation (Category 2) Acute toxicity, Dermal (Category 4) Skin corrosion (Category 1B) . Toxicity . H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. Case Report - Charge. It has been used in pyrotechnics. 7789-09-5. Label Elements. Ammonium dichromate: Class: Small Molecule: Description: Ammonium dichromate is a chemical compound of hexavalent chromium. FIRST AID MEASURES General advice Consult a physician. Authors Menon Narayanankutty Sunilkumar 1 , Thekkuttuparambil Ananthanarayanan Ajith 2 , Vadakut Krishnan Parvathy 1 Affiliations 1 Department of Pediatrics, Amala Institute of Medical Sciences, Thrissur, Kerala, India. Lethal dose of chromium salt varies between 6 to 8 g in adults [ 1 , 2] and 1 g in children. Ammonium Dichromate AR - Hazards statements H272 - May intensify fire; oxidiser. Ammonium dichromate is an inorganic compound with the formula (NH 4) 2 Cr 2 O 7.In this compound, as in all chromates and dichromates, chromium is in a +6 oxidation state, commonly known as hexavalent chromium.It is a salt consisting of ammonium ions and dichromate ions.. Consult a physician.Flush with water for 15 minutes.Get medical assistance if irritation develops. Category 1. H314 - Causes severe skin burns and eye damage. Abstract Full text Similar Articles Ammonium Dichromate Poisoning. CASE REPORT A 48-year-old man drank 150 mL of an aqueous solution containing potassium dichromate 22.5 g in a suicidal attempt and was admitted 7 hours after the ingestion. If breathing is difficult, give oxygen.Poisonous material After skin contact: Take victim to hospital immediately.Remove contaminated clothing and shoes.Wash off with soap and plenty of water. Chromium may increase its own toxicity by modifying metal regulatory transcription factor 1, causing the inhibition of zinc-induced metallothionein transcription. the whole bit Thermal decomposition of ammonium dichromate is initiated by local heating to 190 C. Category 1. H301 Toxic if swallowed. 5J18BP595G. Reproductive toxicity, category 1B H360 Respiratory sensitization, category 1 H334 Skin sensitization, category 1 H317 . Calcium-EDTA therapy had no influence on erythrocyte, serum, or urine chromium level, but contributed, however, to a significant increase in chromium elimination rate in the dialysate. Acute poisoning will result in death due to multi-organ failure. SIGNS AND SYMPTOMS: Ammonium dichromate is irritating to the skin and mucous membranes. H340 May cause genetic defects. UN1439. Ammonium dichromate is an odorless, bright orange to red, crystalline powder used in pyrotechnics, fireworks, photography, and in dyes used for screen and color printing. It is readily ignited and burns to leave a sizable green residue. Product name : Ammonium dichromate Product Number : 402826 Brand : Sigma-Aldrich Supplier : Sigma-Aldrich 3050 Spruce Street SAINT LOUIS MO 63103 USA Telephone : +1 800-325-5832 . ORCIDs linked to this article Parmar K, 0000-0003-2851-5455 himanshu kumar and colleagues from the department of pediatrics, king george's medical university, lucknow, india recently reported an interesting case of ammonium dichromate poisoning.the study is published in the indian journal of pediatrics.chromium (cr) is a strong oxidant and poisoning usually begins with gastrointestinal symptoms Hazard Statements. formula: Cr2H8N2O7 Hazard classification & labelling Hazard classification and labelling The 'Hazard classification and labelling' section shows the hazards of a substance based on the standardised system of statements and pictograms established under the CLP (Classification Labelling and Packaging) Regulation. Chromium (VI) is more toxic than other oxidation states of the chromium atom because of its greater ability to enter cells and higher . Author Citing Papers Author's Papers Author's Citations CAS Registry Number. Open cuts, abraded or irritated skin should not be exposed to this material. "Successful treatment of a patient suffering from severe acute potassium dichromate poisoning with liver transplantation." Transplantation 69(11): 2454-5. Specific target organ toxicity - (repeated exposure) Category 1. The toxicity of ammonium dichromate puts a bit of a potential damper on carbon and gum printing, especially if one want to work in Europe, where availability might soon become a real problem. Sol. : 7789-09-5 Ox. H314 Causes severe skin burns and eye damage. SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1 Product identifiers Product name : Ammonium Dichromate CAS-No. Signal Word. H312 - Harmful in contact with skin. 2 - H272 Carc. Department of Pediatrics, King George's Medical University, Lucknow, India. Product name: Ammonium Dichromate . Authors Citing This Paper. "Chromium occurrence and function in biological systems." . H317 May cause an allergic skin reaction. For disposal: the product of the reaction, the green chromium(III) oxide, Cr 2 O 3 (s), is LOW HAZARD but there may be traces of . If ammonium dichromate is heated in a closed container, it may rupture due to the decomposition of the material. H350 May cause cancer. Acute aquatic toxicity (Category 1), H400 . "Acute ammonium dichromate poisoning." Annals of Emergency Medicine 24(4): 748-50. Chronic aquatic toxicity (Category 1), H410 : GHS Label elements : Acute aquatic toxicity. [ 1] in their statement that the diagnosis of a poisoning case mainly depends on the history, direct identification of the compound, if available and clinical examination. Acute toxicity, Oral (Category 3) Acute toxicity, Inhalation (Category 2) Acute toxicity, Dermal (Category 4) Skin corrosion (Category 1B) : 7789-09-5 . AMMONIUM DICHROMATE Chemwatch: 1439 Version No: 4.1.1.1 Safety Data Sheet according to WHS and ADG requirements Issue Date: 04/12/2017 Print Date: 14/11/2019 . Specific target organ toxicity - repeated exposure (Category 1), H372 . Synonym: Ammonium Bichromate : CAS-No. Mertz, W. (1969). South Plainfield, NJ 07080 . H301 Toxic if swallowed. Absorption of chrome VI compounds through the skin can cause systemic poisoning effecting the kidneys and liver. Ammonium dichromate, ACS, 99.5% min, Thermo Scientific . Ammonium Dichromate can't be shipped by air, its a strong carcinogen etc. H330 Fatal if inhaled. Classified according to Regulation (EU) 1272/2008, Annex VI (Table 3.1/3.2) Serious eye damage/eye irritation Eyes - Rabbit Result: Severe eye irritation NFPA Code H-2 F-1 R-1 OX SECTION 6 ACCIDENTAL RELEASE MEASURES Ventilate area. Average mass 252.065 Da. Ammonium dichromate Acute toxicity LD50 Oral - Rat - 53 mg/kg LC50 Inhalation - Rat - 4 h - 0.2 mg/l - dust/mist LD50 Dermal - Rabbit - 1,860 mg/kg Skin corrosion/irritation Causes skin burns. The target organs that are affected by this poison are the respiratory system, kidneys, liver, eyes and skin. On ingestion, initially there is a relative lack of severe . H314 Causes severe skin burns and eye damage. Acute poisoning will result in death due to multi-organ failure. Chronic aquatic toxicity. System Generated Number. Hexavalent chromium refers to chemical compounds that contain the element chromium in the +6 oxidation state. Circulatory collapse may follow with weak and rapid pulse, shallow respiration, and clammy skin. Kumar H1, Kumar C1, Parmar K2 Author information Affiliations 2 authors 1. 2 - H330 Acute Tox. 1B - H340 Repr. Ammonium dichromate | Cr2H8N2O7 | CID 24600 - structure, chemical names, physical and chemical properties, classification, patents, literature, biological activities . Ammonium dichromate sc-202937 Hazard Alert Code Key: EXTREME HIGH MODERATE LOW Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION . : 7789-09-5 1.2 Relevant identified uses of the substance or mixture and uses advised against Acute . The target organs . Ammonium Dichromate Poisoning Himanshu Kumar1 & Chandrakanta Kumar1 & Kanak Parmar2 Received: 14 October2019/Accepted: 30April 2020 # Dr. K C Chaudhuri Foundation 2020 To the Editor: A 2-year-old boy presented with history of multiple episodes of vomiting, copious mucoid loose stools and sluggishness after one hour of ingestion of unknown . INTRODUCTION Acute oral intoxication with hexavalent chromium compounds is rare, although frequently fatal because of the strong oxidizing effects. Early deaths are generally associated with shock. In case of fire: Use a tri-class dry chemical fire extinguisher (P370+P378). (1, 7, 2, 3, 4) Molecular Formula HCrNO. Poisoning by ammonium dichromate may cause vomiting, pain in the stomach, and metallic taste. Entry into the . Ammonium dichromate is a chemical compound of hexavalent chromium. 1B - H350 Muta. AMMONIUM DICHROMATE 18 07789-09-5 1232-143-1 H8Cr2N207 256.06 g/mol Water 82 7732 -18 -5 H O 18.00 g/mol 4. It is more sensitive to light. H330 Fatal if inhaled. Ammonium dichromate 0.1 - 0.5% CAS No. It has been used in pyrotechnics. H312 Harmful in contact with skin. It acts as a catalyst and a source of nitrogen in the laboratory and as the photoactive site. He was discharged after 4 d of hospital stay. . Acute poisoning will result in death due to multiorgan failure. Poisoning in children by ammonium dichromate, an odorless and bright orange-red crystal, are rarely reported. 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